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| Research Interests and Projects |
My research centers upon an integral component of the global carbon cycle, dissolved organic matter (DOM). All forms of life release DOM, sometimes on purpose, sometimes as waste. DOM lost from one organism provides sustenance to others, including microorganisms at the base of aquatic foodwebs that fuel our fisheries. DOM cycling also redistributes carbon between land, ocean and atmospheric stores. Rivers carry vast amounts of DOM from land to the ocean where most of the global store of DOM resides. As the ocean DOM pool of carbon is equivalent in magnitude to the CO2 pool in the Earth’s atmosphere small shifts in the size of the oceanic DOM pool influence climate.
In addition to its importance as a metabolite and carbon pool, the complexity of DOM makes it incredibly interesting to study. DOM contains thousands, if not millions or trillions, of different molecules. Each derived from a living organism and subsequently altered in the environment. On mass these molecules provide a suite of tracers carrying the signatures of each molecule’s source and subsequent history in the environment. DOMeomics, the decoding of these signatures, is casting new light upon the biogeochemical cycles of the planet. Key to harnessing this information are developments in the characterization of biomolecules which allow us to determine the isotopic, spectral, structural and molecular signatures of DOM. I study these signatures. As DOM is derived from all the life within an ecosystem these messages provide valuable information about the functioning of these ecosystems today and their likely response to local and global change. The information DOM provides is being used to determine the extent of feedbacks between climate, carbon storage and ecosystem function in diverse habitats including glaciers, rivers, the salt marshes at Skidaway, and the open ocean.
Current Projects:
- NSF: DEB-1146161. Collaborative research: Is the export of ancient, labile carbon from glacial ecosystems driven by the deposition of fossil fuel combustion byproducts? A. Stubbins (PI); M. Frischer (both at lead institution SkIO); E. Hood (UAS); R. G. M. Spencer (Woods Hole Research Center); P. Raymond (Yale). $224,037. 3/2012 to 2/14.
- Hanse-Wissenschaftkolleg Fellowship to study the Global Cycle of Dissolved Black Carbon with Thorsten Dittmar, leader of the Max Planck Marine Geochemistry Group (2010-2014).
- Microsoft Research Division. Support for International Geo-Metabolomics workshop at SkIO (2011) and the Hanse-Wissenschaftkolleg, Delmenhorst, Germany (2012).
- NSF: OCE-0850635. Development of a high-precision TOC analyzer with a nM detection limit. K. Mopper (PI) and A. Stubbins. $394,750. 10/2009 to 9/2012.
- NSF: OCE-0728634. Collaborative Research: Comprehensive Chemical Characterization of Marine Dissolved Organic Matter using Efficient Isolation Coupled to Advanced Analytical Techniques. A. Stubbins (PI), K. Mopper, P.G. Hatcher, J-D Mao, and E.M. Perdue. $465,320. 12/2007 to 11/2011.
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Jaffé, R., Y. Ding, J. Niggemann, A. V. Vähätalo, A. Stubbins, R. G. M. Spencer, J. Campbell, and T. Dittmar. 2013. Global charcoal mobilization from soils via dissolution and riverine transport to the oceans. Science 340 (6130): 345-347 doi 10.1126/science.1231476
Spencer, R. G .M., G. R. Aiken, M. M. Dornblaser, K. D. Butler, R. M. Holmes, G. Fiske, P. J. Mann, and A. Stubbins. 2013. Chromophoric dissolved organic matter export from U.S. rivers. Geophysical Research Letters. doi: 10.1002/grl.50357.
Dittmar, T., C. de E. Rezende, M. Manecki, J. Niggemann, A. R. C. Ovalle, A. Stubbins, and M. C. Bernardes. 2012. Continuous flux of dissolved black carbon from a vanished tropical forest biome. Nature Geoscience. doi: 10.1038/NGEO1541.
Stubbins, A., E. Hood, P. A. Raymond, G. R. Aiken, R. L. Sleighter, P. J. Hernes, D. Butman, P. G. Hatcher, R. G. Striegl, P. Schuster, H. A. N. Abdulla, A. W. Vermilyea, D. T. Scott, and R. G. M. Spencer. 2012. Anthropogenic aerosols as a source of ancient dissolved organic matter to glaciers. Nature Geoscience 5: 198-201 doi:10.1038/ngeo1403
Stubbins, A., T. Dittmar, and J. Niggemann. 2012. Photo-lability of oceanic dissolved black carbon. Biogeosciences 9: 1661-1670 doi:10.5194/bg-9-1661-2012
Stubbins, A., and T. Dittmar. 2012. Low volume quantification of dissolved organic carbon and dissolved nitrogen. Limnology and Oceanography: Methods. doi: 10.4319/lom.2012.10.347.
Stubbins, A., C. S. Law, G. Uher, and R. C. Upstill-Goddard. 2011. Carbon monoxide apparent quantum yields and photoproduction in the Tyne estuary. Biogeosciences 8: 703-713.
Stubbins, A., R. G. M. Spencer, H. Chen, P. G. Hatcher, K. Mopper, P. J. Hernes, V. L. Mwamba, A. M. Mangangu, J. N. Wabakanghanzi, and J. Six. 2010. Illuminated darkness: molecular signatures of Congo River dissolved organic matter and its photochemical alteration as revealed by ultrahigh precision mass spectrometry. Limnology and Oceanography 55(4): 1467-1477 doi:10.4319/lo.2010.55.3.1467
Helms, J. R., A. Stubbins, J. D. Ritchie, E. C. Minor, D. J. Kieber, and K. Mopper. 2008. Absorption spectral slopes and slope ratios as indicators of molecular weight, source, and photobleaching of chromophoric dissolved organic matter. Limnology & Oceanography. 53: 955-969.
Stubbins, A., V. Hubbard, G. Uher, G. Aiken, C. S. Law, R. C. Upstill-Goddard, K. Mopper. 2008. Relating carbon monoxide photoproduction to dissolved organic matter functionality. Environmental Science &Technology 42: 3271–3276.
Full Publication List
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